The Bible doesn't explicitly state the ages of most couples, so it's difficult to definitively say whether any women were older than their husbands. However, based on the information provided, there is one possible case.
* Elizabeth and Zechariah: The Gospel of Luke mentions that Elizabeth and Zechariah were both "well advanced in years" when the angel Gabriel appeared to Zechariah to announce that Elizabeth would conceive a child (John the Baptist). While the Bible does not specify their exact ages, it is generally understood that Elizabeth was likely past typical childbearing age. Some interpretations suggest that Elizabeth may have been older than Zechariah, which is possible based on the description of their age and circumstances, but it is not explicitly stated.